Carbon isotope fractionation of chlorinated ethenes during oxidation by Fe2+ activated persulfate
نویسندگان
چکیده
منابع مشابه
Stable carbon isotope fractionation during aerobic biodegradation of chlorinated ethenes.
Stable isotope analysis is recognized as a powerful tool for monitoring, assessing, and validating in-situ bioremediation processes. In this study, kinetic carbon isotope fractionation factors (epsilon) associated with the aerobic biodegradation of vinyl chloride (VC), cis-1,2-dichloroethylene (cDCE), and trichloroethylene (TCE) were examined. Of the three solvents, the largest fractionation ef...
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Compound-specific carbon isotope ratio analysis is a promising tool to assess the origin and fate of organic contaminants in groundwater. The aim of this study was to develop and evaluate a reliable, fast method to determine carbon isotope ratios of chlorinated methanes, ethanes, and ethenes in aqueous samples. Direct solid-phase microextraction (dSPME) and headspace solid-phase microextraction...
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One difficulty in using bioremediation at a contaminated site is demonstrating that biodegradation is actually occurring in situ. The stable isotope composition of contaminants may help with this, since they can serve as an indicator of biological activity. To use this approach it is necessary to establish how a particular biodegradation pathway affects the isotopic composition of a contaminant...
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Activated persulfate oxidation technologies based on sulfate radicals were first evaluated for defluorination of aqueous perfluorooctanesulfonate (PFOS). The influences of catalytic method, time, pH and K2S2O8 amounts on PFOS defluorination were investigated. The intermediate products during PFOS defluorination were detected by using LC/MS/MS. The results showed that the S2O8 (2-) had weak effe...
متن کاملRemediation of total petroleum hydrocarbons using combined in-vessel composting and oxidation by activated persulfate
This study was investigated the efficiency of activated persulfate and in-vessel composting for removal of total petroleum hydrocarbons. Remediation by activated persulfate with ferrous sulfate as pre-treatment was done at batch system. In the chemical oxidation, various variables including persulfate concentrations (10-3000 mg/g as waste), ...
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ژورنال
عنوان ژورنال: Science of The Total Environment
سال: 2012
ISSN: 0048-9697
DOI: 10.1016/j.scitotenv.2012.06.051